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I think that Ralph Waldo Emerson was trying to make a point with this line. People will talk their talk but can they really walk the walk?� Its kinda like the election, they are saying what all they will do, they have really good ideas but will they actually do as they say..you can say something so geniune but when u do something sweet it means more..

I also relate this quote with another saying that a lot of people use today. Have u ever heard someone say "It is easier said than done"?� It is so much easier to say something than actually do it. So Ralph had a big point with his saying.

Has anyone ever just thought of how fucking sad it is that everyone has hopes and dreams of traveling and just�being happy...

And all they need is money. the money.

people blow money every-fuckin-day and don't give a rats ass.

how is that even remotly fair? all those people who just wanna be happy...

it's ridiculous and sad.

On a lighter note:

Life blows.

Thanks for listening dumbfucks.

Heyy guys I am Brooke whats uppp??? :D HEA HEA!!!!! HAHA!!!

I can't remember
Last night's dream
So I'll tell you another

A man
Sits quietly�in his chair
Watching the waves crash into the shoreline

But all around him
Everything is exploding
Like a mirror when it hits the floor

And yet
He sits in his chair
Smiling, like it's the best day of his life
�

and i dont want anyone to read it (:

Isocyanates with two or more functional groups are required for the formation of polyurethane polymers. Volume wise, aromatic isocyanates account for the vast majority of global diisocyanate production. Aliphatic and cycloaliphatic isocyanates are also important building blocks for polyurethane materials, but in much smaller volumes. There are a number of reasons for this. First, the aromatically linked isocyanate group is much more reactive than the aliphatic one. Second, aromatic isocyanates are more economical to use. Aliphatic isocyanates are used only if special properties are required for the final product. For example, light stable coatings and elastomers can only be obtained with aliphatic isocyanates. Even within the same class of isocyanates, there is a significant difference in reactivity of the functional groups based on steric hindrance. In the case of 2,4-toluene diisocyanate, the isocyanate group in the para position to the methyl group is much more reactive than the isocyanate group in the ortho position.

Phosgenation of corresponding amines is the main technical process for the manufacture of isocyanates. The amine raw materials are generally manufactured by the hydrogenation of corresponding nitro compounds. For example, toluenediamine (TDA) is manufactured from dinitrotoluene, which then converted to toluene diisocyanate (TDI). Diamino diphenylmethane or methylenedianiline (MDA) is manufactured from nitrobenzene via aniline, which is then converted to diphenylmethane diisocyanate (MDI).

The two most important aromatic isocyanates are toluene diisocyanate (TDI) and diphenylmethane diisocyanate (MDI). TDI consists of a mixture of the 2,4- and 2,6-diisocyanatotoluene isomers. The most important product is TDI-80 (TD-80), consisting of 80% of the 2,4-isomer and 20% of the 2,6-isomer. This blend is used extensively in the manufacture of polyurethane flexible slabstock and molded foam.¹² TDI, and especially crude TDI and TDI/MDI blends can be used in rigid foam applications, but have been supplanted by polymeric MDI. TDI-polyether and TDI-polyester prepolymers are used in high performance coating and elastomer applications. Prepolymers are available that have been vacuum stripped of TDI monomer, which greatly reduces their toxicity. Diphenylmethane diisocyanate (MDI) has three isomers, 4,4'-MDI, 2,4'-MDI, and 2,2'-MDI, and is also polymerized to provide oligomers of functionality three and higher.

Only the 4,4'-MDI monomer is sold commercially as a single isomer. It is provided either as a frozen solid or flake, or in molten form, and is used to manufacture high performance prepolymers. Monomer blends, consisting of approximately 50% of the 4,4'-isomer and 50% of the 2,4'-isomer, are liquid at room temperature and are used to manufacture prepolymers for polyurea spray elastomer applications. 4,4'-MDI blends containing MDI uretonimine, carbodiimide, and allophonate moieties are also liquid at room temperature, and are used in the manufacture of integral skin and microcellular foams. 4,4'-MDI-glycol prepolymers offer increased mechanical properties in the same applications, but are prone to freezing at temperatures below 20�C. Polymeric MDI (PMDI) is used in rigid pour-in-place, spray foam, and molded foam applications. Polymeric MDI that contains a very high portion of high-functionality oligomers is used to manufacture polyurethane and polyisocyanurate rigid insulation boardstock. Modified PMDI, which contains high levels of MDI monomer, is used in the production of polyurethane flexible molded and microcellular foam. The relative percentage of the 4,4'- and 2,4'- isomers is adjusted to change the reactivity and storage stability of the isocyanate blend, as well as the firmness and other physical properties of the finished goods. Other aromatic isocyanate include p-phenylene diisocyante (PPDI), naphthalene diisocyanate (NDI), and o-tolidine diisocyanate (TODI).

The most important aliphatic and cycloaliphatic isocyanates are 1,6-hexamethylene diisocyanate (HDI), 1-isocyanato-3-isocyanatomethyl-3,5,5-trimethyl-cyclohexane (isophorone diisocyanate, IPDI), and 4,4'-diisocyanato dicyclohexylmethane (H₁₂MDI). They are used to produce light stable, non-yellowing polyurethane coatings and elastomers. Because of their toxicity, aliphatic isocyanate monomers are converted into prepolymers, biurets, dimers, and trimers for commercial use. HDI adducts are used extensively for weather and abrasion resistant coatings and lacquers. IPDI is used in the manufacture of coatings, elastomeric adhesives and sealants. H₁₂MDI prepolymers are used to produce high performance coatings and elastomers with optical clarity and hydrolysis resistance. Other aliphatic isocyanates include cyclohexane diisocyanate (CHDI), tetramethylxylene diisocyanate (TMXDI), and 1,3-bis(isocyanatomethyl)cyclohexane (H₆XDI).

Sunday Nov 28 2008. Start trying InboxJournal.com

Have you ever been verbally slaughtered because of your beliefs? Do you feel like the whole world is collapsing on top of you? How about feeling like no one understands the situation you're in?

Believing in God is difficult especially in the times we are currently living. Sometimes, I feel like the whole world is against me because of that. But I have to remember that I'm never alone. And also, that life isn't a sprint, so I can take my time because the God I believe in is patient, merciful, and loving. And that He will always be waiting for you, even when you turn away from Him. He will never reject you, no matter how many bad things you've done. He DOESN'T need you, yet He cares for you more deeply than you'll ever understand. He's the only one that can fill the emptiness in your heart, and can give you hope in the midst of your worst storm. He can show you so much more than what you can see or understand at the moment. He is simply wonderful. =)

Wow. I can't believe it's already been 6 months since that last post. A lot has happened since then..

1. I started to see a Psychologist. I actually went once in late April; I went to my school's Counseling Center and set up an appointment. After that initial visit, I think I was more angry than ever. All the lady did was say "mmhmm", "okay", "that must have been terrible", etc, all in the most cheesy fake voice ever. I was so frustrated with her!�After that, our schedules weren't quite in synch so I didn't see her again.. my school only allows students to seek help while they're enrolled, so once summer started and I wasn't taking any classes, I couldn't see her.

2. I went back on Monday the 19th. Mostly because I found out from a relative two-and-a-half weeks ago that my mom had an abnormal pap smear, and was going to have to have a biopsy done to see if it was cancer. Well, to make a long story short, my mom actually called me after I found out, and we cried on the phone a lot, but I told her I was worried about her. It really made me realize that even though I hate my parents for some of the things they've done/the way they've treated me, I still would care if something bad happened to them. That fact really confused the hell out of me, so I made an appointment with Dr. F (the psychologist I saw in April).

3. Mom's fine. She texted me that her results came back "precancerous" which means she just has to go back every 6 months for 3 years, and she'll pretty much be fine. Can you believe she TEXTED me that?! I at least expected a phone call.. the nerve of her!

4. I've been pretty mellow lately, with only a few (one or two) bitchy outbursts since April. However... R (my boyfriend) has been really really rude.. like when I don't understand something within seconds after he says it and I ask him a question, he gets SO�angry and tells me I'm an idiot. I have been reacting really slowly lately, especially to things I should be quick with (i.e. I've always been good at math, but for some reason can't add correctly lately??)

That's it for now.. I'll write again soon (Dr. F is "requiring" me to start journaling on a more frequent basis to get my feelings out)

Christina

So today was a pretty good day. I did really good at work. I think i might actually be getting better at it.� I did what I needed to do. But now what.....I need to think about how imma advance in life.�I need to start school but with what time and will power. lord knows I lack that. I just need to focus and do shit . I still wonder about what will happen with us. I just kinda hope for the best. I'm trying to be as possitive as I�can be but it's hard not knowing.�Sometimes I'm so focused and then I'm just not. need to think more......

Got up late today. I let the alarm ring a bunch of times. Yesterday, I took too long to sleep and I paid for it� by waking up really late. Anyway, after my regular morning cup o joe, I didn't have time for breakfast and I didn't drink much water either. Its 2:15pm now and I'm only drinking my first glass of water. L&L BBQ chicken for lunch, tho. That was yummy. We'll see how the lack of water affects my swim tonight.�

Well, I can't find out whether the lack of water was going to affect my swim. I did't take my bikini bottom to the gym so no swimming. Did some Christmas shopping instead. So its spaghetti for dinner and hopefully sleep early. Have to make a delivery in Gardena tomorrow so I won't be riding to work tomorrow. Mayber Thursday. Also, Cory's gig at the Marmiton was canned cause the restaurant closed down. What a drag. Thats gotta smart.

�Yesterday I recieved a note from an old friend. We were friends all through Middle School when she moved here,but then it all seemed to change within these last two years. In our Junior year we were still hanging out an just not talking at school. Sadly now that we are seniors,she doesn't talk to me at all. Her boyfriend doesn't like her talking to me so she doesn't want to cause a fight with him by talking to me.

You see yesterday she gave me a note at the end of the day telling me that she wanted to be my friend, but she didn't want anyone to know about it. She kept telling me her boyfriend would get mad about it. That and we don't hang with the same group of friends anymore so she doesn't want her group or my group to know that we are talking. I am not allowed to text her unless we are in school otherwise I have to write her notes and talk to her that way.

I don't know how to respond to this at all. I mean we use to be good friends,but now that she has a boyfriend, she seems to good for me. That and her new group she hangs with hates me with a passion and I don't like them either. They just think they are better than the rest and they use to be some of my friends before we all hit high school.

I don't know if I should just go along with this and just stick to texting during school and writing notes back in forth or just give up. I don't feel like she can truely want to be my friend if she wants to hide our friendship. Please if anyone can give me some advice on this. If she makes a good point and I should just try and make this work or just stick with my gut and not give a care about it. Please if you could give me some advice let me know.

Thanks!